FERRIC CITRATE NHYD
FERRIC CITRATE
CAS: 2338-05-8
Molecular Formula: C6H5FeO7·H2O
FERRIC CITRATE NHYD - Names and Identifiers
FERRIC CITRATE NHYD - Physico-chemical Properties
| Molecular Formula | C6H5FeO7·H2O |
| Molar Mass | 262.96 |
| Boling Point | 309.6℃ at 760mmHg |
| Water Solubility | Soluble in water |
| Appearance | Form Solid, color Garnet red powder |
| Storage Condition | RT, dark |
| Stability | Stable. Light sensitive. |
| Physical and Chemical Properties | Chemical properties reddish brown transparent flakes or brown powder. The aqueous solution is acidic and can be gradually reduced to ferrous citrate under the influence of light and heat. Dissolve slowly in water, hot water is more soluble than cold water. Insoluble in ethanol. |
| Use | Use of nutritional supplements (iron fortification). Added to biscuits, modified milk powder and wheat flour. Used in India for table salt. |
FERRIC CITRATE NHYD - Risk and Safety
| WGK Germany | 3 |
| FLUKA BRAND F CODES | 8 |
FERRIC CITRATE NHYD - Upstream Downstream Industry
FERRIC CITRATE NHYD - Nature
| Odor | Odorless |
| hydrolysis sensitivity | 0: forms stable aqueous solutions |
| Merck | 13,4050 |
| EPA chemical information | 1,2,3-Propanetricarboxylic acid, 2-hydroxy-, iron salt (2338-05-8) |
Last Update：2024-04-09 01:59:50
FERRIC CITRATE NHYD - Uses and synthesis methods
identification test
positive for citrate test (IT-13) and iron salt test (IT-19).
content analysis
accurately weigh about 1g of the sample, move it into a glass plug flask at the grinding port, add 5ml of hydrochloric acid and 25ml of water, heat and dissolve it, add 4g of potassium iodide after cooling, place it in a dark chamber for 15min after plucking, add 100ml of water, titrate free iodine with 0.1mol/L, sodium thiosulfate solution, and use starch test solution (TS-235) as indicator. At the same time, a blank test was conducted. 0.1mol/L sodium thiosulfate solution per Ml is equivalent to 5.585mgFe.
Toxicity
dogs were fed orally at an amount of 1~2mg/kg, and symptoms of poisoning occurred, while 10mg/kg died. Subcutaneous injection of iron can occur
use limited
GB 14880-94(mg/kg): cereals and their products, 150~290; Beverage 60~120; Dairy products, infant formula food, 360~600; Salt, sandwich sugar, 3600~7200.
use
1. As a food iron fortifier, the absorption effect is better than inorganic iron. China stipulates that it can be used for salt and sandwich sugar, and the usage amount is 3600~7200 mg/kg; 1000~1200 mg/kg in high-iron cereals and their products (50g of such foods are limited daily); 360~600 mg/kg in dairy products and infant food; 150~290 mg/kg in cereals and their products; 60~120 mg/kg in beverages.
2. As a food iron fortifier, the absorption effect is better than inorganic iron. China stipulates that it can be used for salt and sandwich sugar, with a usage of 3600-7200mg/kg; 1000-1200mg/kg in high-iron cereals and their products (50g of such foods are limited daily); 360-600mg/kg in dairy products and infant food; 150-290mg/kg in cereals and their products; 60-120mg/kg in beverages.
3. As a food additive, it is added to biscuits, milk powder and flour, as an iron nutrition fortifier, and also as a feed additive. Iron citrate is also used as a medicine, as a photosensitive paper for blueprints, etc.
production method
1. add ammonia water to ferric sulfate solution to generate ferric hydroxide precipitation. Filter and wash with water until there is no sulfuric acid reaction. Add citric acid, heat to below 60°C under stirring, dissolve all the precipitate, and filter. The filtrate is heated and concentrated into a syrup shape below 60°C, and coated on a glass plate into a thin layer to form small leaves, peeled off, warmed, and dried.
2. Add ammonia water to the ferric sulfate solution to generate ferric hydroxide precipitate; then filter, wash with water until there is no sulfuric acid reaction, then add citric acid, and heat to 60 ℃ to dissolve all the precipitate; finally filter, Concentrate the filtrate to the form of syrup, coat it on a glass plate, and peel it off to form a small flake product after slight temperature drying.
3. add citric acid to iron hydroxide solution, heat at a temperature lower than 60 ℃, evaporate to slurry, apply to glass plate, dry at low temperature to form small flakes, and peel them off.
category
Corrosive Substances
flammability hazard characteristics
Flammable, hot and irritating smoke from the fire scene
storage and transportation features
The warehouse is low temperature, ventilated and dry; stored separately from strong oxidants
fire extinguishing agent
Water, carbon dioxide, dry powder, sand
Last Update：2024-04-09 21:01:54
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Spot supply
Product Name: Iron(III) citrate tribasic monohydrate Visit Supplier Webpage Request for quotationCAS: 2338-05-8
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409
Wechat: 18301782025
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Raw Materials for FERRIC CITRATE NHYD